李贵贤,曾晓亮,贠宏飞,李强,李红伟,边杰.水热法制备Cu-HMS催化剂及其催化草酸二甲酯加氢性能的研究[J].分子催化编辑部,2018,32(1):1-7
水热法制备Cu-HMS催化剂及其催化草酸二甲酯加氢性能的研究
Preparation of Cu-HMS Catalysts by Hydrothermal Method and Study on Catalytic Hydrogenation Performance of Dimethyl Oxalate
投稿时间:2017-12-11  修订日期:2018-01-10
DOI:
中文关键词:  水热合成法  铜负载量  Cu-HMS催化剂  草酸二甲酯  乙二醇
英文关键词:hydrothermal synthesis method  copper loading  Cu-HMS catalyst  dimethyl oxalate  ethylene glycol
基金项目:
作者单位
李贵贤 兰州理工大学 石油化工学院, 甘肃 兰州 730050 
曾晓亮 兰州理工大学 石油化工学院, 甘肃 兰州 730050 
贠宏飞 兰州理工大学 石油化工学院, 甘肃 兰州 730050 
李强 兰州理工大学 石油化工学院, 甘肃 兰州 730050 
李红伟 兰州理工大学 石油化工学院, 甘肃 兰州 730050 
边杰 兰州理工大学 石油化工学院, 甘肃 兰州 730050 
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中文摘要:
      以十六胺为模板剂,采用水热合成法制备了一系列不同铜负载量的Cu-HMS催化剂,并考察了其对草酸二甲酯加氢制乙二醇反应的催化性能.同时,通过X射线粉末衍射(XRD)、N2低温吸附脱附、红外光谱(FI-IR)、H2程序升温还原(H2-TPR)及透射电镜(TEM)等手段对催化剂进行了系统表征.结果表明,铜负载量对催化剂活性组分的分散性和载体之间的相互作用力影响很大.实验结果表明,以20%铜负载量制备的Cu-HMS催化剂催化性能优势明显.在反应温度为205℃、压力为2.0 MPa、氢酯比为80 mol/mol及液时空速为0.4 h-1的条件下,草酸二甲酯的转化率接近100%,乙二醇的选择性高达98.11%.
英文摘要:
      A series of Cu-HMS catalysts with different copper loadings were prepared by hydrothermal synthesis method using hexadecylamine as template, the catalytic performance of the Cu-HMS catalyst for the hydrogenation of dimethyl oxalate to ethylene glycol was investigated. At the same time, the catalysts were systematically characterized by X-ray diffraction (XRD), N2 cryogenic adsorption and desorption, fourier transform infrared spectroscopy (FT-IR), H2 temperature program reduction (H2-TPR) and transmission electron microscopy (TEM) and other means. The results show that copper loading has a great influence on the dispersibility of active components and the interaction force between supports. The experimental results show that the catalytic performance of Cu-HMS catalyst prepared at 20% copper loading is obvious advantages. At the reaction temperature of 205℃, the pressure of 2.0 MPa, the molar ratio of hydrogen to ester of 80 mol/mol and the liquid hourly space velocity of 0.4 h-1. The conversion of dimethyl oxalate was close to 100% and the selectivity to ethylene glycol was up to 98.11%.
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