陈松丛,韩峰,刘建华,夏春谷,马建霞.离子液体共价键功能化氧化石墨烯负载催化材料催化反应研究进展[J].分子催化,2018,32(4):382-396 |
离子液体共价键功能化氧化石墨烯负载催化材料催化反应研究进展 |
Progress in Catalysis of Ionic Liquid Covalently Functionalized Graphene Oxide Supported Catalysts |
投稿时间:2018-05-15 修订日期:2018-06-30 |
DOI: |
中文关键词: 氧化石墨烯 离子液体 催化 功能化 |
英文关键词:graphene oxide ionic liquid catalysis functionalization |
基金项目:国家自然科学基金项目(No.21673260;21373248;71373260),甘肃省科技厅项目(17ZC1LA017) |
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中文摘要: |
氧化石墨烯由于其独特的结构和性能赋予了它作为催化剂的先天优势,功能化的氧化石墨烯为其应用领域的拓展和效果提升提供了更多的发展契机,成为目前的研究趋势,离子液体功能化的氧化石墨烯结合二者自身优势的基础上,并由于协同作用具有更加优异的催化性能,广泛应用于众多反应中.我们针对离子液体共价键功能化的氧化石墨烯负载催化剂常见的催化反应,包括环加成反应,氧化反应,偶联反应,酯交换反应,乌尔曼反应,重排反应,光催化和电催化在近年来的研究进展进行了相关综述. |
英文摘要: |
The unique structure and properties ofgraphene oxide give it inherent advantages as a catalyst. The functionalized graphene oxide provides more opportunities for development and improvement of its application fields. It has become the current research trend. The ionic liquids functionalized graphene oxide combines both its own advantages with graphene oxide and ionic liquid and has more excellent catalytic performance due to synergistic effect. This review summarizes the common catalytic reactions of ionic liquid functionalized graphene oxide supported catalysts, including cycloaddition reaction, oxidation reaction, coupling reaction, transesterification reaction, Ullmann reaction, rearrangement reaction, photocatalysis and electrocatalysis reaction, etc. |
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