| 方伟国,姚小兰,杨继东,崔芳.生物基甘油氢解合成1,3-丙二醇催化剂的研究进展[J].分子催化,2018,32(6):581-593 |
| 生物基甘油氢解合成1,3-丙二醇催化剂的研究进展 |
| Research Progress of Catalysts in Hydrogenolysis of Bioglycerol to 1,3-Propanediol |
| 投稿时间：2018-09-17 修订日期：2018-10-19 |
| DOI： |
| 中文关键词: 生物基甘油 1,3-丙二醇 氢解反应 反应机理 研究进展 |
| 英文关键词:bio-glycerol 1,3-propanediol hydrogenolysis reaction mechanism research advance |
| 基金项目:甘肃省青年科技基金（1606RJYA309）；甘肃省科技支撑计划（1604FKCA113）. |
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| 中文摘要: |
| 1，3-丙二醇（1，3-PDO）作为聚酯单体原料有广阔的市场空间，在化妆品和医药等领域也被广泛应用.由生物基甘油选择氢解一步法合成1，3-PDO工艺被认为是一条绿色环保和高经济性的技术路线.我们在这里主要介绍了甘油氢解制备1，3-PDO催化剂的研究进展，对催化剂类型、催化剂的合成方法和工艺条件进行了归类总结；分析了多种催化剂体系的甘油氢解反应机理，指出了该反应工业化过程中存在的一些问题，并展望了今后的研究发展方向. |
| 英文摘要: |
| 1,3-propanediol as an important polyester raw material has a broad market space, and is also widely used in cosmetics and medicine. One-pot selective hydrogenolysis of biomass-derived glycerol is regarded as a green and economic technology route for the production of 1,3-propanediol. This review focused on the development of catalysts in the hydrogenolysis of glycerol to 1,3-propanediol. The type of the catalysts used in this reaction and their synthetics methods and proccess conditions were summaried. Reaction mechanisms of glycerol deoxygenation to 1,3-propanediol in different catalyst systems were analyzed. The problems existed in the process of industrialization of this reaction and some prospects were also pointed out. |
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