| 胡一鸣,郑万彬,汤岑,李艳明,鲁继青.贵金属催化剂上巴豆醛选择性加氢的研究进展[J].分子催化,2020,34(4):366-377 |
| 贵金属催化剂上巴豆醛选择性加氢的研究进展 |
| Recent Advances in Selective Hydrogenation of Crotonaldehyde over Noble Metal Catalysts |
| 投稿时间：2020-06-01 修订日期：2020-06-22 |
| DOI： |
| 中文关键词: 巴豆醛 选择性加氢 Ir基催化剂 Pt基催化剂 |
| 英文关键词:crotonaldehyde selective hydrogenation Ir-based catalyst Pt-based catalyst |
| 基金项目:国家自然科学基金（No.21773212，21643007） |
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| 中文摘要: |
| 巴豆醛是一种重要的α，β-不饱和醛，其选择性加氢常被用作模型反应用以研究催化剂构效关系.近年来，文献报道了众多贵金属基催化剂上巴豆醛选择性加氢的结果.我们主要从贵金属催化剂角度系统地讨论和总结该反应的最新进展.通过比较催化剂的不同反应行为，进一步明确催化剂性质（如催化剂结构、晶面/界面效应、电子效应和几何效应等）与反应性能之间的关系.并尝试总结和讨论当前研究中所存在的不足与前景，为进一步提高目标产物的收率提供思路. |
| 英文摘要: |
| Crotonaldehyde is an important α,β-unsaturated aldehyde and its selective hydrogenation is often used as a model reaction to study the structure-activity relationship of catalysts. In recent years, the results of selective hydrogenation of crotonaldehyde over many noble metal catalysts have been reported. This review mainly summarizes the latest progress of this reaction from the perspective of noble metal catalysts. By comparing the different reaction behaviors of catalysts, the relationship between the properties of catalysts (such as catalyst structure, crystal/interface effect, electronic effect and geometric effect) and the reaction performance is discussed. And perspective of catalyst design is also discussed to further improve the catalytic performance. |
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