赵重阳,李国波,眭华军,刘初明,王玲,张亚平.砷中毒商业V2O5-WO3/TiO2催化剂再生研究[J].分子催化编辑部,2020,34(5):407-414
砷中毒商业V2O5-WO3/TiO2催化剂再生研究
Study on Regeneration of Commercial V2 O5-WO3/TiO2 Catalyst for Arsenic Poisoning
投稿时间:2020-06-12  修订日期:2020-08-22
DOI:
中文关键词:  SCR  催化剂  As中毒  再生
英文关键词:selective catalytic reduction  catalyst  arsenic poisoning  regeneration
基金项目:江苏省重点研发计划(社会发展)面上项目(BE2017716)
作者单位E-mail
赵重阳 国家能源集团谏壁发电厂, 江苏 镇江 212006  
李国波 东南大学 能源与环境学院, 江苏 南京 210096  
眭华军 国家能源集团谏壁发电厂, 江苏 镇江 212006  
刘初明 国家能源集团谏壁发电厂, 江苏 镇江 212006  
王玲 东南大学 能源与环境学院, 江苏 南京 210096  
张亚平 东南大学 能源与环境学院, 江苏 南京 210096 amflora@seu.edu.cn 
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中文摘要:
      采用FeCl3和2,4,6-三巯基三嗪(TMT)溶液分别清洗再生砷(As)中毒商业V2O5-WO3/TiO2催化剂,通过BET、XRD、XRF、in situ DRIFTS以及H2-TPR等表征方法对清洗再生前后催化剂理化性质进行分析.研究发现,清洗后催化剂脱硝活性有极大地恢复,20 mg·mL-1 FeCl3和0.5% TMT溶液再生30 min时最佳As去除率分别为83.67%和94.57%.清洗后,阻塞在催化剂微孔和中孔中的AsOx被清除,因此再生后催化剂比表面积和孔体积均有所增大而平均孔径略有减小.同时,FeCl3和2,4,6-TMT溶液清洗再生后催化剂表面Brønsted和Lewis酸强度均有所增加,这可能是再生催化剂催化性能提高的主要原因.
英文摘要:
      FeCl3 and 2,4,6-trimercaptotriazine (TMT) solutions were used to clean and regenerate arsenic (As) poisoned commercial V2O5-WO3/TiO2 catalysts. A comparative study of physico-chemical properties between poisoned and regenerated catalysts was carried out by Brunauer-Emmette-Teller (BET), X-ray diffraction (XRD), X-ray fluorescence (XRF), in situ infrared spectrometry (in situ IR), and temperature programmed reduction of H2 (H2-TPR). It was found that the catalyst’s denitration activity was greatly restored after cleaning. Regeneration by 20 mg·mL-1 FeCl3 and 0.5% TMT solution for 30 min exhibited best As removal ratio of 83.67% and 94.57%, respectively. The micropores and mesopores which blocked by As oxides were cleaned, thus the specific surface area, pore volume increased and the average pore diameter decreased. Meanwhile, the Brønsted and Lewis acid strengths of the catalyst surface increased after FeCl3 and 2,4,6-TMT solution cleaning and regeneration, which might be the main reason for the improvement of catalytic performance over the regenerated catalysts.
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