| 王征,蔺庆,张相龙,马宁,刘松.γ-和δ-酮酸衍生物均相催化氢化研究进展[J].分子催化,2021,35(2):178-187 |
| γ-和δ-酮酸衍生物均相催化氢化研究进展 |
| Recent Progress in Homogeneous Catalytic Hydrogenation of γ- and δ-Ketoacid Derivatives |
| 投稿时间：2020-10-22 修订日期：2020-12-10 |
| DOI：10.16084/j.issn1001-3555.2021.02.009 |
| 中文关键词: 氢化反应 金属有机配合物 生物质 γ-和δ-酮酸衍生物 内酯 |
| 英文关键词:hydrogenation organometallic complexes biomass γ- and δ-ketoacid derivatives lactones |
| 基金项目:河北农业大学引进人才专项启动基金（YJ201931）；河北农业大学林学院学科群建设基金 |
|
| 摘要点击次数: 468 |
| 全文下载次数: 624 |
| 中文摘要: |
| γ-和δ-酮酸衍生物是最重要的双官能团生物质平台化合物之一，如何高效地催化这些酮酸类化合物转化成相应的单一精细化学品是当今研究的难点.我们综述了金属有机配合物均相催化氢化γ-和δ-酮酸的最新进展，重点介绍了用于催化生产γ-和δ-羟基酸、酯、内酯、环醚等的均相催化剂的结构、活性、选择性和反应机理. |
| 英文摘要: |
| γ- and δ-Ketoacid derivatives are one of the most important bifunctional biomass platform compounds. How to efficiently catalyze the hydrogenation of these ketoacid derivatives into the corresponding single fine chemicals is a difficult issue in the current research. This review focuses on recent progress related to homogeneously hydrogenated γ-/δ-keto acids catalyzed by metal-organic complexes as well as mainly introduces on the structure, activity, selectivity and reaction mechanism of homogeneous catalysts for the catalytic production of γ- and δ-hydroxy acids, esters, lactones, cyclic ethers, etc. |
| HTML 查看全文 查看/发表评论 下载PDF阅读器 |
