| 马红竹,索继栓.MnTFPPCl模拟体系催化环己烯氧化反应性能研究[J].分子催化,1999,(3):165-168 |
| MnTFPPCl模拟体系催化环己烯氧化反应性能研究 |
| Oxidation of Cyclohexene Catalyzed by Mn() Tetrakis(Pentafluorophenyl) Porphyrin |
| |
| DOI： |
| 中文关键词: 高氟代 金属卟啉 锰卟啉 环己烯 氧化 催化剂 |
| 英文关键词:Tetrakis(pentafluorophenyl)porphyrin,Single oxygen atom donor,Axial
ligand, |
| 基金项目: |
| 马红竹 索继栓 |
| 中国科学院兰州化学物理研究所，西安石油学院工作 |
| 摘要点击次数: 1054 |
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| 中文摘要: |
| 研究了高氟代金属卟啉ＭｎＴＦＰＰＣｌ催化环己烯氧化反应的催化活性，探索了反应体系中不同单氧原子给体对催化反应的影响。结果表明，ＭｎＴＦＰＰ－Ｃｌ／ＮａＯＣｌ体系有较好的催化转移氧能力。主要以ＰｈＩＯ为氧化剂，考察了轴向配体，溶剂等对ＭｎＴＦＰＰＣｌ／ＰｈＩＯ模拟体系的影响。 |
| 英文摘要: |
| In this paper the catalytic activity of metalloporphyrin
was studied. Influences of oxidant and axial ligand on cyclohexene oxidation catalyzed by this
catalyst were also investigated. The results indicated thatthe system of MnTFPPCl/NaOCl was
superior as compared to other systems. The effects of axial ligand were different for various
oxidants. In addition,the influence of solvent on the system of MnTFPPCl/PhIO was also
investigated. |
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