傅利勇,吕绍洁.碱性助剂的添加对Ni/CaO-Al2O3催化剂性能的影响[J].分子催化,2000,(3):179-183 |
碱性助剂的添加对Ni/CaO-Al2O3催化剂性能的影响 |
Effect of Basic Promotors on the Performance of Ni/CaO-Al2O3 Catalysts |
修订日期:1999-10-25 |
DOI: |
中文关键词: 碱性助剂 合成气 甲烷 二氧化碳 催化剂 性能 |
英文关键词:Basic promotors,Synthesis gas,Methane,Carbon dioxide, |
基金项目: |
傅利勇 吕绍洁 |
中国科学院成都有机化学研究所,天然气转化开放实验室,成都,610041 |
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中文摘要: |
在CH4、 CO2和O2制合成气的反应中, 通过在Ni/CaO-Al2O3催化剂中添加碱性助剂K2O、 MgO和La2O3, 使催化剂的性能得到了改善. 实验结果表明, MgO和La2O3助剂的添加, 有利于提高催化剂的活性;添加K2O, 却相反. 测得催化剂上积炭量的顺序为: Ni-La2O3/CaO-Al2O3 |
英文摘要: |
In the reaction of CH 4, CO 2 and O 2 to synthesis gas, the catalyst performances were improved when basic promotors, such as K 2O, MgO and La 2O 3, were added to Ni/CaO Al 2O 3 catalyst. The experimental results show that, addition of MgO and La 2O 3 increases the activity of catalyst, but the effect of K 2O is opposite, and the order of the carbon deposition amount on catalysts is: NiO La 2O 3/CaO Al 2O 3 |
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