| 蔡迎春,丑凌军,张兵,赵军,李树本.Mn-CaO催化剂上甲烷-二氧化碳共活化制C2烃研究Ⅰ.反应性能的研究[J].分子催化,2005,(4):271-274 |
| Mn-CaO催化剂上甲烷-二氧化碳共活化制C2烃研究Ⅰ.反应性能的研究 |
| Selective Conversion of CH4 and CO2 to C2 Hydrocarbons over Mn-CaO Catalysts I. Study on the Catalytic Performance |
| 投稿时间：2004-12-21 修订日期：2005-02-26 |
| DOI： |
| 中文关键词: 甲烷 二氧化碳 C2烃 |
| 英文关键词:Mn-CaO |
| 基金项目:甲烷及液化石油气选择氧化制高级烃（Grant20373081）. |
| 蔡迎春 丑凌军 张兵 赵军 李树本 |
| 中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,甘肃兰州730000 |
| 摘要点击次数: 1137 |
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| 中文摘要: |
| 考察了不同组成Mn-Ca0催化剂上甲烷一二氧化碳转化制C2烃反应性能，同时考察了反应温度，CO2分压对反应性能的影响及催化反应性能随时间的变化。 |
| 英文摘要: |
| To conversion of CH_ 4 and CO_ 2 to C_ 2 Hydrocarbons, a series of Mn-CaO catalysts were prepared using coprecipitation method and the catalytic performance were studied. CH_ 4 and CO_ 2 conversion increase With Mn content increase, while C_ 2 selectivity decreases. The best catalytic performance was obtained over the Mn-CaO catalyst with a Mn/Ca ratio of 1/1 and the maximum C_ 2 yield 3.0% was obtained over it. Effects of reaction temperature, CO_ 2 partial pressure on the catalytic performance of Mn-CaO(Mn/Ca1) were investigated. The change in reaction performance with time on stream was also studied. |
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