| 李贵贤,董鹏.Ru/HY催化剂催化对苯二酚加氢研究[J].分子催化,2012,(1):26-31 |
| Ru/HY催化剂催化对苯二酚加氢研究 |
| Study of Catalytic Hydrogenation of 1, 4-Benzenediol over Ru/HY catalyst |
| 投稿时间：2011-12-02 修订日期：2012-01-10 |
| DOI： |
| 中文关键词: Ru/HY催化剂 催化加氢 对苯二酚 1,4-环己二醇 机理 |
| 英文关键词:Ru/HY catalyst Catalytic hydrogenation 1, 4-Benzenediol 1, 4-Cyclohexanediol Mechanism |
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| 中文摘要: |
| 对苯二酚液相加氢制备1,4-环己二醇的途径环境友好。关键是研究高催化活性的催化剂来提高产物产率。本文以Ru/HY为催化剂用于对苯二酚加氢。也通过XRD, TEM对催化剂进行了表征,通过吡啶吸收红外对HY酸性的变化进行了讨论。对其反应条件进行了优化。3.0 wt% Ru/HY的催化剂表现出高的活性，结果表明对苯二酚的转化率和1,4-环己二醇的选择性分别为96.46 %和68.25 %。基于对Ru/HY催化剂结构的研究探讨并提出相应的反应机理。 |
| 英文摘要: |
| Liquid-phase catalytic hydrogenation of 1, 4-benzenediol is an environmentally friendly routine for 1, 4-cyclohexanediol production. The key to increasing product yield is to develop catalysts with high catalytic performance. In this work, Ru/HY catalysts were prepared and applied to the hydrogenation of 1, 4-benzenediol to 1, 4-cyclohexanediol. The activity of catalyst was investigated by XRD, TEM. The change of the HY acid content was discussed by Pyridine adsorption infrared. The optimal reaction conditions were investigated. 3.0 wt% Ru/HY catalyst exhibited high activity with conversion of 1, 4-benzenediol and selectivity of 1, 4-cyclohexanediol up to 96.46 % and 68.25 %, respectively. Furthermore, based on the study of Ru/HY’ structure, a plausible reaction mechanism for the selective formation of 1, 4-benzenediol was proposed. |
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