| 苏二正.深共熔溶剂及其生物催化应用[J].分子催化,2015,(4):390-401 |
| 深共熔溶剂及其生物催化应用 |
| Deep Eutectic Solvents and their applications in Biocatalysis |
| 投稿时间：2015-08-11 修订日期：2015-08-24 |
| DOI： |
| 中文关键词: 绿色化学 深共熔溶剂 毒性 生物催化 |
| 英文关键词:Green chemistry, Deep Eutectic Solvents, Physical-chemistry properties, Biocatalysis |
| 基金项目:国家自然科学基金项目（面上项目，重点项目，重大项目） |
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| 摘要点击次数: 2052 |
| 全文下载次数: 7100 |
| 中文摘要: |
| 在绿色化学研究领域，溶剂占据着重要的位置。作为一个绿色溶剂必须满足廉价易得、可生物降解、无毒、可循环使用、无挥发性等标准的要求。但是至今能满足这些要求的溶剂仍然非常有限。近年来，深共熔溶剂（Deep Eutectic Solvents，DESs）被认为可以作为绿色溶剂替代传统的有机溶剂而受到广泛关注。DESs是由两个或多个成分在特定比例下形成的凝固点大大降低室温液态混合物。与离子液体相比，DESs具有廉价、低毒、可生物降解等特点，在许多领域成为研究热点。本文综述了DESs的生物降解性、毒性/细胞毒性及其作为生物催化反应介质的研究现状。基于对研究现状的认识，对DESs未来研究、应用需要解决的问题进行了讨论。作者期望对DESs生物催化应用研究现状的综述更进一步促进DESs研究、应用的发展。 |
| 英文摘要: |
| Within the framework of green chemistry, solvents occupy a strategic place. To be qualified as a green medium, the solvent has to meet different criteria such as availability, non-toxicity, biodegradability, recyclability, flammability, and low price among others. Up to now, the number of available green solvents is rather limited. In recent years, deep eutectic solvents (DESs) have been considered green solvent alternatives to conventional solvents and have attracted considerable attention. DESs are defined as a mixture of two or more components, which may be solid or liquid and that at a particular composition present a high melting point depression becoming liquids at room temperature. DESs are considered as a new class of ionic liquids (ILs). Comparing to traditional ILs, DESs are low-toxic, biodegradable, the price is generally low and their performances can be adjusted. Owing to these remarkable advantages, DESs are now of growing interest in many fields of research. This paper summarizes the toxicity and biodegradability of DESs, and the applications of DESs in biocatalysis. Future perspectives on the major directions toward the research on DESs are also discussed. This work is expected to be helpful for the further development of DESs based on a summary of the research in the field of biocatalysis. |
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