| 高芳芳,陈静,黄志威,夏春谷.生物质基呋喃衍生物选择氢解制备戊二醇和己二醇研究进展[J].分子催化,2018,32(3):276-293 |
| 生物质基呋喃衍生物选择氢解制备戊二醇和己二醇研究进展 |
| Recent Advances in the Selective Hydrogenolysis of Biomass-based Furan Derivatives to Pentanediols and Hexanediol |
| 投稿时间：2017-12-20 修订日期：2018-03-10 |
| DOI： |
| 中文关键词: 生物质 呋喃衍生物 选择氢解 戊二醇 己二醇 |
| 英文关键词:biomass furan derivatives selective hydrogenolysis pentanediols hexanediol |
| 基金项目:国家自然科学基金（21473224）；中国科学院青年创新促进会（2016371）；苏州科技发展计划（SYG201626） |
|
| 摘要点击次数: 1391 |
| 全文下载次数: 2377 |
| 中文摘要: |
| 生物质基呋喃衍生物来源广泛，利用生物糠醛、5-羟甲基糠醛及他们的衍生物选择氢解制备戊二醇、己二醇具有重要的研究价值和意义.根据原料和催化剂体系不同对生物质基呋喃衍生物选择氢解制备高碳二元醇的代表性工作进行了归纳总结，对影响催化剂活性和选择性的关键因素如活性金属、载体、助剂及反应溶剂等进行了分析讨论，对反应可能涉及的路径和机理进行了阐述，并对未来的研究方向和发展趋势作了展望. |
| 英文摘要: |
| The selective hydrogenolysis of abundant biomass-based furan derivatives in nature, including furfural (FA), 5-hydroxymethylfurfural (5-HMF) and their derivatives, into pentanediols and hexanediol is significant for academic research and industrial application. The representative works on the selective hydrogenolysis of biomass-based furan derivatives into high-carbon glycols were summarized according to the different raw materials and catalyst systems. The important factors for activity and selectivity consisting of active metal, carrier, additives and solvents were remarked. The possible reaction pathways and mechanism were demonstrated, and prospect for the research directions as well as future development was proposed. |
| HTML 查看全文 查看/发表评论 下载PDF阅读器 |
