| 黄锦,汪伟.钯和四齿膦配体催化剂应用于Heck反应的研究[J].分子催化,2018,32(4):342-348 |
| 钯和四齿膦配体催化剂应用于Heck反应的研究 |
| Palladium-Tetraphosphine Catalyzed Heck Coupling Reaction |
| 投稿时间：2018-05-19 修订日期：2018-07-19 |
| DOI： |
| 中文关键词: Heck反应 钯 四齿膦配体 |
| 英文关键词:Heck reaction palladium tetraphosphine ligand |
| 基金项目:国家自然科学基金（No.21602144）；四川省科技计划资助（2018JY0485） |
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| 中文摘要: |
| 设计合成了以联萘二胺为骨架的四齿膦配体N，N，N'，N'-四（二苯基膦甲基）-（1，1'-联萘）-2，2'-二胺，并将其与钯组成的催化体系用于苯乙烯和芳卤的Heck反应，该催化体系对各种卤代芳烃都表现出了很高的催化活性.对活化底物对溴苯腈，即使底物与催化剂的物质的量比达到10 000，反应20 h几乎能达到定量转化；该催化体系对活性更低的杂环底物也取得了良好的催化效果. |
| 英文摘要: |
| The catalytic performance of tetraphosphine based on binaphthyldiamine as backbone, N,N,N',N'-tetra-[(diphenylphosphino)methyl]-1,1'-binaphthalene-2,2'-diamine, combined with palladium for the Heck reactions of styrene and aryl halides was investigated. This system could catalyze a variety of aryl halide substrates with a wide range of functional groups as well as heteroaryl halides. The yield of 99% was obtained with activated 4-bromobenzonitrile even the molar ratio of substrate to catalyst up to 10 000. |
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