| 潘茵茵,宋广杰,薛宽荣,许胜.非合成气法烯烃、炔烃氢甲酰化研究进展[J].分子催化,2021,35(2):166-177 |
| 非合成气法烯烃、炔烃氢甲酰化研究进展 |
| The Development of Hydroformylation of Alkenes and Alkynes with Syngas Substitutes |
| 投稿时间：2020-10-10 修订日期：2020-11-29 |
| DOI：10.16084/j.issn1001-3555.2021.02.008 |
| 中文关键词: 烯烃 炔烃 非合成气 氢甲酰化 |
| 英文关键词:syngas substitutes hydroformylation reaction alkenes alkynes |
| 基金项目:国家重点研发计划重点基础材料技术提升与产业化重点专项 |
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| 中文摘要: |
| 烯烃、炔烃的氢甲酰化反应是制备醛及其衍生物的重要反应，传统的过渡金属催化合成气（CO/H2）合成法，因为价格低廉，工艺成熟，在工业上得到了广泛应用.然而合成气的高毒性、高危性限制了它的实验室研究，因此使用非合成气的氢甲酰化反应吸引了化学家的研究兴趣.采用非一氧化碳（CO）为羰基源的新型氢甲酰化研究发展迅速，我们对该领域近20年的发展进行综述，针对合成气替代物甲醛（HCHO），二氧化碳（CO2），甲酸（HCOOH），（缩）乙醛酸（HOOCCHO）丁醛以及多元醇等优缺点进行了详细的讨论，并对该领域发展方向予以展望. |
| 英文摘要: |
| Hydroformylation of alkenes and alkynes is an important reaction for the preparation of aldehydes and their derivatives. Traditional synthesis methods using syngas (CO/H2) as substrates have achieved great success in industry. However, syngas is toxicity and risk, limiting its laboratory research and application. In recent years, hydroformylation with syngas substitutes has attracted much attention in the organic synthesis. New hydroformylation with syngas substitutes has been developed rapidly. In this paper, the development of hydroformylation in recent years was reviewed. The alternatives to syngas such as HCHO, CO2, HCOOH, glyoxylic acid and alcohol are introduced one by one. Finally, the future development of hydroformylation is prospected. |
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