| 刘宝华,赵华华,杨建,赵军,闫亮,宋焕玲,丑凌军.乙烷选择氧化制乙酸的研究进展[J].分子催化,2021,35(5):484-494 |
| 乙烷选择氧化制乙酸的研究进展 |
| Research Progress of Ethane Oxidation to Acetic Acid |
| 投稿时间：2021-03-12 修订日期：2021-04-22 |
| DOI：10.16084/j.issn1001-3555.2021.05.009 |
| 中文关键词: 选择氧化 Mo-V催化剂 Mars-van-Krevelen 活性中心 |
| 英文关键词:selective oxidation Mo-V catalyst Mars-van-Krevelen active centre |
| 基金项目:中国石油科技创新基金2019D-5007-0404；中国科学院青年创新促进会（2017460） |
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| 中文摘要: |
| 乙烷选择氧化制乙酸是缓解资源短缺、实现低碳烷烃高附加值利用的重要技术.该反应常用的催化剂有杂多酸、钒磷氧化物以及多金属氧化物，其中多金属氧化物催化剂，尤其是Mo-V体系，由于具有高的热稳定性和好的催化活性被广泛研究.我们从催化剂的性质、反应动力学及反应机理方面综述了Mo-V催化剂在乙烷选择氧化制乙酸方面的研究进展. |
| 英文摘要: |
| Selective oxidation of ethane to acetic acid is an important technology to relieve the shortage of resources and realize the high value-added utilization of light alkane. There are have heteropoly acids, vanadium phosphorus oxide and multi-metal oxide catalysts for this reaction, the multi-metal oxide catalyst among them, especially the Mo-V system, have been extensively researched due to possess high thermal stability and good catalytic activity. In this article, from the aspects of catalysts properties, reaction kinetics and reaction mechanism in selective oxidation of ethane to acetic acid on Mo-V catalysts are reviewed. |
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