| 刘玮,高永乐,蒋丽佳,段婷婷,黄彩艳,戎梅竹.掺杂多孔碳材料催化醇选择性氧化研究进展[J].分子催化,2023,37(6):559-568 |
| 掺杂多孔碳材料催化醇选择性氧化研究进展 |
| Research Progress on Catalyzed Selective Oxidation of Alcohols by Doped Porous Carbon Materials |
| 投稿时间：2023-05-15 修订日期：2023-07-16 |
| DOI：10.16084/j.issn1001-3555.2023.06.005 |
| 中文关键词: 掺杂多孔碳材料 醇 选择性氧化 催化 |
| 英文关键词:doped porous carbon alcohol selective oxidation catalysis |
| 基金项目:国家自然科学基金(21662047)；云南省自然科学基金地区项目(2013FZ044) |
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| 中文摘要: |
| 羰基化合物是重要的有机中间体, 醇类化合物的选择性氧化是合成羰基化合物的一类重要反应. 在这类反应中, 掺杂多孔碳材料因其独特的性能可直接作为催化剂或者催化剂载体. 我们综述了单一掺杂多孔碳材料、共掺杂多孔碳材料和负载型掺杂多孔碳材料的制备方法, 可能存在的活性位点和催化机理. 最后, 讨论了掺杂多孔碳材料目前需要解决的问题, 指出设计绿色高效的负载非贵金属的掺杂多孔碳材料是未来的一个重要发展方向. |
| 英文摘要: |
| Carbonyl compounds are important organic intermediates, and selective oxidation of alcohol compounds is an important reaction for the synthesis of carbonyl compounds. In this type of reaction, doped porous carbon materials can be directly used as catalysts or catalyst carriers because of their unique properties. The preparation methods of single doped porous carbon materials, co-doped porous carbon materials and supported doped porous carbon materials are reviewed, and the possible active sites and catalytic mechanisms are pointed out. Finally, the problems that need to be solved in the current problem of doped porous carbon materials are discussed, and the design of green and efficient doped porous carbon materials loaded with non-precious metals is a future development direction. |
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