| 王诗怡,罗明生,张子扬.MOFs材料在COx加氢制醇反应中的研究进展[J].分子催化,2024,38(4):386-398 |
| MOFs材料在COx加氢制醇反应中的研究进展 |
| Research Progress in the Application of MOFs Materials in COx Hydrogenation to Alcohols |
| 投稿时间：2024-02-26 修订日期：2024-04-25 |
| DOI：10.16084/j.issn1001-3555.2024.04.009 |
| 中文关键词: 合成气转化 COx加氢 低碳醇 MOFs |
| 英文关键词:syngas conversion COx hydrogenation low-carbon alcohols MOFs |
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| 中文摘要: |
| 传统燃料燃烧过程中排放的CO2/CO会导致环境的日益恶化, 通过热催化将CO2/CO还原成高附加值的醇类是应对和解决环境恶化问题的有效途径之一. 然而, 要得到收率和选择性高的产物, 需要设计高效的催化剂来提高CO2/CO加氢的催化活性. MOFs材料由于其独特的物理化学性质和高度可调性等特点, 在加氢催化领域受到了人们的广泛关注. 因此, 我们系统地阐述了MOFs材料在碳氧化物COx加氢制醇反应中的研究进展, 总结了碳氧化物加氢制醇的部分反应机理, 同时对MOFs材料应用于COx加氢反应的性能表现和合成方法进行了初步探讨. |
| 英文摘要: |
| The escalating emissions of CO2/CO during conventional fuel combustion have exacerbated environmental deterioration. A promising avenue to mitigate this environmental challenge is catalytic reduction of CO2/CO into high-value alcohols through thermal catalysis. However, achieving high yields and selectivity necessitates designing efficient catalysts to augment CO2/CO hydrogenation catalytic activity. MOFs materials have garnered substantial attention in hydrogenation catalysis owing to their unique physical and chemical properties and high tunability. Hence, we comprehensively review the research advancements of MOFs materials in COx hydrogenation for alcohol synthesis, elucidate partial reaction mechanisms of carbon oxide hydrogenation for alcohol synthesis, and provide preliminary insights into the performance and synthesis methods of MOFs materials employed in COx hydrogenation reactions. |
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